By Gordon P. Bierwagen (Eds.)
content material: Corrosion and its keep watch over by way of coatings / Gordon P. Bierwagen --
long term electrochemical impedance spectroscopy and electrochemical reviews of 5 targeted kinds of military coatings / J.N. Murray --
program of localized electrochemical impedance spectroscopy to the examine of the degradation of natural coatings / F. Zou and D. Thierry --
Electrochemical impedance research of anticorrosive latex paint movies / Carleton J. Barbour --
program of impedance spectroscopy throughout the life of natural coatings / D.H. van der Weijde, E.P.M. van Westing, G.M. Ferrari, and J.H.W. de Wit --
utilizing reliability statistics to estimate metal-container failure degrees from censored exams / W. Stephen Tait --
Quantification of coating getting older utilizing impedance measurements / E.P.M. van Westing, D.H. van der Weijde, M.P.W. Vreijling, G.M. Ferrari, and J.H.W. de Wit --
learn of the water barrier homes of paints after ordinary and sped up photooxidative degradation / E. Deflorian, L. Fedrizzi, and P.L. Bonora --
reports of adhesion and disbonding of coatings by means of scanning acoustic microscopy / J.D. Crossen, J.M. Sykes, G.A.D. Briggs, and J.P. Lomas --
Defects and heterogeneities in corrosion protecting natural coatings motion pictures and their results on movie functionality / Gordon P. Bierwagen, Dennis E. Tallman, Joel Zlotnick, and Carol S. Jeffcoate --
Prediction of blistering in coating structures / James M. Pommersheim and T. Nguyen --
preliminary stories of electrochemical comparability of coating functionality in flowing as opposed to desk bound electrolyte / Carol S. Jeffcoate and Gordon P. Bierwagen --
delivery houses of waterborne polymeric coatings / H.K. Tay and J.M. Sykes --
Degradation of polymer coatings on metal uncovered to seawater / F. Mansfeld, H. Xiao, L.T. Han, and C.C. Lee --
Failure mode prediction of natural coating-metallic substrate structures / L. Nicodemo, T. Monetta, and F. Bellucci --
Biodegradation of polyimide-coated chromium substrates / D.B. Mitton, S. Toshima, S.S. Chang, R.M. Latanision, F. Bellucci, T.E. Ford, J.-D. Gu, and R. Mitchell --
Quantitative equipment of predicting relative effectiveness of corrosion-inhibiting coatings on plane aluminum / K.J. Lewis, J.H. Aklian, and J.D. Zook --
Inhibition homes of a few airplane corrosion protecting coatings / A.W. Fangmeier, E. Kock, F. Vohwinkel, and C.P. Brandt --
checking out of coating fabrics in commercial perform / Otto Vogt --
real looking functionality trying out of inner coatings for oilfield construction / G.R. Ruschau --
a facet of concrete defense via floor coating / J.B. Johnson and B.S. Skerry --
Formulations and box functionality of fluorinated polyurethane coatings / Robert F. Brady, Jr. --
Electrochemical experiences of vinyl ester coatings for gasoline tanks / V.N. Balbyshev, Gordon P. Bierwagen, and R.L. Berg --
keep watch over of the protecting houses of polyethylene coatings utilizing molybdenum disulphide filling / V. Yu. Barinov, V.E. Panasyuk, and S.R. Prots --
disorder region calculated from electrochemical noise and impedance measurements / R.L. Twite and Gordon P. Bierwagen --
Novel pretreatments of metals for corrosion defense by means of coatings. half 1, Plasma polymerized hexamethyldisiloxane on cold-rolled metal / W.J. van Ooij and K.D. Conners --
Novel pretreatments of metals for corrosion safeguard by means of coatings. half 2, Plasma polymerized hexamethyldisiloxane motion pictures on galvalume / W.J. van Ooij, N. Tang, S.-E. Hörnström, and J. Karlsson --
development of wet-adhesion on stainless steels via electrolytic polymerization remedy with triazine thiol compounds / H. Yamabe --
The alternative of chromate- and lead-based inhibitors in protecting coatings / Charles Simpson --
unhazardous spinel-type pigments in anticorrosive coatings / A. Kalendová, J. Snupárek, and P. Kalenda --
Anticorrosion natural coatings ready from aniline oligomers and their epoxy-cured derivatives / Yen Wei, Chuncai Yang, Jui-Ming Yeh, Tianzhong Ding, Gu Wei, Danliang Jin, Jianguo Wang, Xinru Jia, and Susan A. Jansen --
Polyaniline in corrision-resistant coatings / T. web page McAndrew, Susan A. Miller, Andrew G. Gilicinski, and Lloyd M. Robeson --
Corrosion inhibition utilizing self-assembled monolayers of alkanethiols on copper / G. Kane Jennings and Paul E. Laibinis --
Corrosion safeguard with natural acid sealants for anodized aluminum / Garson P. Shulman and Albert J. Bauman --
Electrochemical houses of coatings from renewable normal items / U.G. Hermann, Gordon P. Bierwagen, D.J. generators, and V.H. Hauser.
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Extra info for Organic Coatings for Corrosion Control
The high frequency loop defined with a characteristic frequency of 30-40 Hz is probably due to charge transfer while the low frequency loops probably corresponds to the kinetic of intermediate species in the dissolution path of iron in the vicinity of the defect. From figure 5d, it is obvious that the low frequency region transforms in a negative resistance loop characteristic of the passivation after 5 hours of exposure in 10 mM NaCl. The present results are in good agreement to previous work performed with traditional EIS on iron in neutral and basic mediae.
1988, 88, 109-124. 16. Brasher, D. ; Kingsbury, A. H. J. Appl. Chem. 1954, 4, 62. 17. ; Nicodemo L. Corrosion, 1993, 49(3), 235-247. 18. ; Nicolais L. Polymer News, 1992, 17, 272-277. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1998. Chapter 5 Application of Impedance Spectroscopy During the Lifetime of Organic Coatings 1 2 2 1 D. H. van der Weijde , Ε. P. M. van Westing , G. M. Ferrari , and J. H. W. O. Box 57, 1780 AB Den Helder, Netherlands In this paper the use of Electrochemical Impedance Spectroscopy is evaluated for three situations during the lifetime of organic barrier coating.
As long as the coatings were not damaged the behaviour of the CPE parameters in time was similar to that shown in Figure 2. The coating resistance was too high to be determined accurately from the measurements. Figure 2. The behaviour of the CPE parameters of a coating during prolonged immersion in an electrolyte. W. ; W a s h i n g t o n , D C 20036 ACS Symposium Series; American Chemical Society: Washington, DC, 1998. 48 General Behaviour In the beginning an almost Fickian water absorption can be seen, followed by a region of non-Fickian behaviour due to secondary effects like curing, relaxation, swelling etc.